Week 1

Lecture 1, 22 January, 13.15-15.00, FL51

Introductory lecture.
Historical review of electron theory of solids.
Classification of solids. Binding in solids. Itinerant electrons.

Reading

A&M: Chapter 19, 20.

Review questions

1. What is the difference between molecular and ionic crystals?
2. What is Van der Waals interaction?
3. Describe electron density distribution in covalent crystals and metals. What causes electron delocalization?

Home task

1. A&M: problem 19.1 a-d.
2. Calculate energy of classical dipole-dipole interaction.


Lecture 2, 24 January, 10.00-12.00, FL51

Failure of the classical electron theory.
Fermi gas of free electrons. Degeneracy temperature, Fermi energy, Fermi momentum.
Fermi distribution. Thermodynamics of free electrons.

Reading

A&M: Chapter 1 (pp. 6-11, 20-25), 2
L&L: Par. 53, 57-60

Review questions

1. What is the ground state of electron gas?
2. What is the Fermi energy? Fermi momentum? Express these quantities through electron density.
3. Derive equation for density of states of 3D (2D, 1D) electrons.
4. Calculate total energy, pressure of the Fermi gas at T=0.
5. Derive Fermi distribution. What is chemical potential? What is the low-temperature limit for electron gas? Give an estimate for corresponding temperature for typical metals.
6. Calculate energy of electron gas at low temperature. What is the idea behind Sommerfeld expansion?
7. Calculate specific heat of the Fermi electrons. Explain the concept of "effective" electrons.